Class for calculating the equation of state of water. More...

#include <WaterPropsIAPWS.h>

Collaboration diagram for WaterPropsIAPWS:

Public Member Functions
	WaterPropsIAPWS ()
	Base constructor. More...

	WaterPropsIAPWS (const WaterPropsIAPWS &right)=delete

WaterPropsIAPWS &	operator= (const WaterPropsIAPWS &right)=delete

void	setState_TR (doublereal temperature, doublereal rho)
	Set the internal state of the object wrt temperature and density. More...

doublereal	helmholtzFE () const
	Calculate the Helmholtz free energy in mks units of J kmol-1 K-1, using the last temperature and density. More...

doublereal	Gibbs () const
	Calculate the Gibbs free energy in mks units of J kmol-1 K-1. More...

doublereal	enthalpy () const
	Calculate the enthalpy in mks units of J kmol-1 using the last temperature and density. More...

doublereal	intEnergy () const
	Calculate the internal energy in mks units of J kmol-1. More...

doublereal	entropy () const
	Calculate the entropy in mks units of J kmol-1 K-1. More...

doublereal	cv () const
	Calculate the constant volume heat capacity in mks units of J kmol-1 K-1 at the last temperature and density. More...

doublereal	cp () const
	Calculate the constant pressure heat capacity in mks units of J kmol-1 K-1 at the last temperature and density. More...

doublereal	molarVolume () const
	Calculate the molar volume (kmol m-3) at the last temperature and density. More...

doublereal	pressure () const
	Calculates the pressure (Pascals), given the current value of the temperature and density. More...

doublereal	density (doublereal temperature, doublereal pressure, int phase=-1, doublereal rhoguess=-1.0)
	Calculates the density given the temperature and the pressure, and a guess at the density. More...

doublereal	density_const (doublereal pressure, int phase=-1, doublereal rhoguess=-1.0) const
	Calculates the density given the temperature and the pressure, and a guess at the density, while not changing the internal state. More...

doublereal	density () const
	Returns the density (kg m-3) More...

doublereal	temperature () const
	Returns the temperature (Kelvin) More...

doublereal	coeffThermExp () const
	Returns the coefficient of thermal expansion. More...

doublereal	coeffPresExp () const
	Returns the isochoric pressure derivative wrt temperature. More...

doublereal	isothermalCompressibility () const
	Returns the coefficient of isothermal compressibility for the state of the object. More...

doublereal	dpdrho () const
	Returns the value of dp / drho at constant T for the state of the object. More...

doublereal	psat_est (doublereal temperature) const
	This function returns an estimated value for the saturation pressure. More...

doublereal	psat (doublereal temperature, int waterState=WATER_LIQUID)
	This function returns the saturation pressure given the temperature as an input parameter, and sets the internal state to the saturated conditions. More...

doublereal	densSpinodalWater () const
	Return the value of the density at the water spinodal point (on the liquid side) for the current temperature. More...

doublereal	densSpinodalSteam () const
	Return the value of the density at the water spinodal point (on the gas side) for the current temperature. More...

int	phaseState (bool checkState=false) const
	Returns the Phase State flag for the current state of the object. More...

doublereal	Tcrit () const
	Returns the critical temperature of water (Kelvin) More...

doublereal	Pcrit () const
	Returns the critical pressure of water (22.064E6 Pa) More...

doublereal	Rhocrit () const
	Return the critical density of water (kg m-3) More...

Private Member Functions
void	calcDim (doublereal temperature, doublereal rho)
	Calculate the dimensionless temp and rho and store internally. More...

void	corr (doublereal temperature, doublereal pressure, doublereal &densLiq, doublereal &densGas, doublereal &delGRT)
	Utility routine in the calculation of the saturation pressure. More...

void	corr1 (doublereal temperature, doublereal pressure, doublereal &densLiq, doublereal &densGas, doublereal &pcorr)
	Utility routine in the calculation of the saturation pressure. More...

Private Attributes
WaterPropsIAPWSphi	m_phi
	pointer to the underlying object that does the calculations. More...

doublereal	tau
	Dimensionless temperature, tau = T_C / T. More...

doublereal	delta
	Dimensionless density, delta = rho / rho_c. More...

int	iState
	Current state of the system. More...

Detailed Description

Class for calculating the equation of state of water.

This is a helper class for WaterSSTP and PDSS_Water and does not constitute a complete implementation of a thermo phase by itself (see Thermodynamic Properties and classes WaterSSTP and PDSS_Water).

The reference is W. Wagner, A. Pruss, "The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use," J. Phys. Chem. Ref. Dat, 31, 387, 2002.

This class provides a very complicated polynomial for the specific Helmholtz free energy of water, as a function of temperature and density.

\[ \frac{M\hat{f}(\rho,T)}{R T} = \phi(\delta, \tau) = \phi^o(\delta, \tau) + \phi^r(\delta, \tau) \]

where

\[ \delta = \rho / \rho_c \quad \mathrm{and} \quad \tau = T_c / T \]

The following constants are assumed

\[ T_c = 647.096\mathrm{\;K} \]

\[ \rho_c = 322 \mathrm{\;kg\,m^{-3}} \]

\[ R/M = 0.46151805 \mathrm{\;kJ\,kg^{-1}\,K^{-1}} \]

The free energy is a unique single-valued function of the temperature and density over its entire range.

Note, the base thermodynamic state for this class is the one used in the steam tables, such that the liquid at the triple point for water has the following properties:

u(273.16, rho) = 0.0
s(273.16, rho) = 0.0
psat(273.16) = 611.655 Pascal
rho(273.16, psat) = 999.793 kg m-3

Therefore, to use this class within Cantera, offsets to u() and s() must be used to put the water class onto the same basis as other thermodynamic quantities. For example, in the WaterSSTP class, these offsets are calculated in the following way. The thermodynamic base state for water is set to the NIST basis here by specifying constants EW_Offset and SW_Offset. These offsets are calculated on the fly so that the following properties hold:

Delta_Hfo_idealGas(298.15, 1bar) = -241.826 kJ/gmol
So_idealGas(298.15, 1bar) = 188.835 J/gmolK

The offsets are calculated by actually computing the above quantities and then calculating the correction factor.

This class provides an interface to the WaterPropsIAPWSphi class, which actually calculates the \( \phi^o(\delta, \tau) \) and the \( \phi^r(\delta, \tau) \) polynomials in dimensionless form.

All thermodynamic results from this class are returned in dimensional form. This is because the gas constant (and molecular weight) used within this class is allowed to be potentially different than that used elsewhere in Cantera. Therefore, everything has to be in dimensional units. Note, however, the thermodynamic basis is set to that used in the steam tables. (u = s = 0 for liquid water at the triple point).

This class is not a ThermoPhase. However, it does maintain an internal state of the object that is dependent on temperature and density. The internal state is characterized by an internally stored \( \tau\) and a \( \delta \) value, and an iState value, which indicates whether the point is a liquid, a gas, or a supercritical fluid. Along with that the \( \tau\) and a \( \delta \) values are polynomials of \( \tau\) and a \( \delta \) that are kept by the WaterPropsIAPWSphi class. Therefore, whenever \( \tau\) or \( \delta \) is changed, the function setState() must be called in order for the internal state to be kept up to date.

The class is pretty straightforward. However, one function deserves mention. The density() function calculates the density that is consistent with a particular value of the temperature and pressure. It may therefore be multivalued or potentially there may be no answer from this function. It therefore takes a phase guess and a density guess as optional parameters. If no guesses are supplied to density(), a gas phase guess is assumed. This may or may not be what is wanted. Therefore, density() should usually at least be supplied with a phase guess so that it may manufacture an appropriate density guess. density() manufactures the initial density guess, nondimensionalizes everything, and then calls WaterPropsIAPWSphi::dfind(), which does the iterative calculation to find the density condition that matches the desired input pressure.

The phase guess defines are located in the .h file. they are

WATER_GAS
WATER_LIQUID
WATER_SUPERCRIT

There are only three functions which actually change the value of the internal state of this object after it's been instantiated

setState_TR(temperature, rho)
density(temperature, pressure, phase, rhoguess)
psat(temperature, waterState);

The setState_TR() is the main function that sets the temperature and rho value. The density() function serves as a setState_TP() function, in that it sets internal state to a temperature and pressure. However, note that this is potentially multivalued. Therefore, we need to supply in addition a phase guess and a rho guess to the input temperature and pressure. The psat() function sets the internal state to the saturated liquid or saturated gas state, depending on the waterState parameter.

Because the underlying object WaterPropsIAPWSphi is privately held, you can be sure that the underlying state of this object doesn't change except due to the three function calls listed above.

Definition at line 162 of file WaterPropsIAPWS.h.

Constructor & Destructor Documentation

◆ WaterPropsIAPWS()

WaterPropsIAPWS ( )

Base constructor.

Definition at line 38 of file WaterPropsIAPWS.cpp.

Member Function Documentation

◆ setState_TR()

void setState_TR	(	doublereal	temperature,
		doublereal	rho
	)

Set the internal state of the object wrt temperature and density.

Parameters

temperature	temperature (kelvin)
rho	density (kg m-3)

Definition at line 580 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::calcDim(), WaterPropsIAPWS::delta, WaterPropsIAPWS::m_phi, WaterPropsIAPWS::tau, WaterPropsIAPWSphi::tdpolycalc(), and WaterPropsIAPWS::temperature().

Referenced by WaterPropsIAPWS::density(), PDSS_Water::dthermalExpansionCoeffdT(), WaterSSTP::satPressure(), WaterSSTP::setDensity(), PDSS_Water::setDensity(), PDSS_Water::setState_TR(), WaterSSTP::setTemperature(), and PDSS_Water::setTemperature().

◆ helmholtzFE()

doublereal helmholtzFE ( ) const

Calculate the Helmholtz free energy in mks units of J kmol-1 K-1, using the last temperature and density.

Definition at line 62 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWS::m_phi, WaterPropsIAPWSphi::phi(), Cantera::Rgas, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

◆ Gibbs()

doublereal Gibbs ( ) const

Calculate the Gibbs free energy in mks units of J kmol-1 K-1.

using the last temperature and density

Definition at line 267 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWSphi::gibbs_RT(), WaterPropsIAPWS::m_phi, Cantera::Rgas, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by WaterSSTP::getGibbs_RT(), WaterSSTP::getStandardChemPotentials(), and PDSS_Water::gibbs_mole().

◆ enthalpy()

doublereal enthalpy ( ) const

Calculate the enthalpy in mks units of J kmol-1 using the last temperature and density.

Definition at line 586 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWSphi::enthalpy_RT(), WaterPropsIAPWS::m_phi, Cantera::Rgas, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by PDSS_Water::enthalpy_mole(), and WaterSSTP::getEnthalpy_RT().

◆ intEnergy()

doublereal intEnergy ( ) const

Calculate the internal energy in mks units of J kmol-1.

Definition at line 593 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWSphi::intEnergy_RT(), WaterPropsIAPWS::m_phi, Cantera::Rgas, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by WaterSSTP::getIntEnergy_RT(), and PDSS_Water::intEnergy_mole().

◆ entropy()

doublereal entropy ( ) const

Calculate the entropy in mks units of J kmol-1 K-1.

Definition at line 600 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWSphi::entropy_R(), WaterPropsIAPWS::m_phi, and Cantera::Rgas.

Referenced by PDSS_Water::entropy_mole(), and WaterSSTP::getEntropy_R().

◆ cv()

doublereal cv ( ) const

Calculate the constant volume heat capacity in mks units of J kmol-1 K-1 at the last temperature and density.

Definition at line 606 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWSphi::cv_R(), WaterPropsIAPWS::m_phi, and Cantera::Rgas.

Referenced by PDSS_Water::cv_mole(), and WaterSSTP::cv_mole().

◆ cp()

doublereal cp ( ) const

Calculate the constant pressure heat capacity in mks units of J kmol-1 K-1 at the last temperature and density.

Definition at line 612 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWSphi::cp_R(), WaterPropsIAPWS::m_phi, and Cantera::Rgas.

Referenced by PDSS_Water::cp_mole(), and WaterSSTP::getCp_R().

◆ molarVolume()

doublereal molarVolume ( ) const

Calculate the molar volume (kmol m-3) at the last temperature and density.

Definition at line 618 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, Cantera::M_water, and Cantera::Rho_c.

Referenced by PDSS_Water::molarVolume().

◆ pressure()

doublereal pressure ( ) const

Calculates the pressure (Pascals), given the current value of the temperature and density.

The density is an independent variable in the underlying equation of state

Returns: the pressure (Pascal)

Definition at line 70 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWS::m_phi, Cantera::M_water, WaterPropsIAPWSphi::pressureM_rhoRT(), Cantera::Rgas, Cantera::Rho_c, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by WaterPropsIAPWS::corr(), WaterPropsIAPWS::corr1(), WaterPropsIAPWS::density(), WaterPropsIAPWS::density_const(), PDSS_Water::pressure(), and WaterSSTP::pressure().

◆ density() [1/2]

doublereal density	(	doublereal	temperature,
		doublereal	pressure,
		int	phase = `-1`,
		doublereal	rhoguess = `-1.0`
	)

Calculates the density given the temperature and the pressure, and a guess at the density.

Sets the internal state.

Note, below T_c, this is a multivalued function.

The density() function calculates the density that is consistent with a particular value of the temperature and pressure. It may therefore be multivalued or potentially there may be no answer from this function. It therefore takes a phase guess and a density guess as optional parameters. If no guesses are supplied to density(), a gas phase guess is assumed. This may or may not be what is wanted. Therefore, density() should usually at least be supplied with a phase guess so that it may manufacture an appropriate density guess. density() manufactures the initial density guess, nondimensionalizes everything, and then calls WaterPropsIAPWSphi::dfind(), which does the iterative calculation to find the density condition that matches the desired input pressure.

Parameters

temperature	Kelvin
pressure	Pressure in Pascals (Newton/m**2)
phase	guessed phase of water; -1: no guessed phase
rhoguess	guessed density of the water; -1.0 no guessed density

Returns: the density. If an error is encountered in the calculation the value of -1.0 is returned.

Definition at line 78 of file WaterPropsIAPWS.cpp.

References Cantera::M_water, Cantera::P_c, WaterPropsIAPWS::pressure(), Cantera::Rgas, Cantera::Rho_c, WaterPropsIAPWS::setState_TR(), Cantera::T_c, and WaterPropsIAPWS::temperature().

Referenced by WaterProps::coeffThermalExp_IAPWS(), WaterProps::density_IAPWS(), PDSS_Water::dthermalExpansionCoeffdT(), and WaterProps::isothermalCompressibility_IAPWS().

◆ density_const()

doublereal density_const	(	doublereal	pressure,
		int	phase = `-1`,
		doublereal	rhoguess = `-1.0`
	)		const

Calculates the density given the temperature and the pressure, and a guess at the density, while not changing the internal state.

Note, below T_c, this is a multivalued function.

The density() function calculates the density that is consistent with a particular value of the temperature and pressure. It may therefore be multivalued or potentially there may be no answer from this function. It therefore takes a phase guess and a density guess as optional parameters. If no guesses are supplied to density(), a gas phase guess is assumed. This may or may not be what is wanted. Therefore, density() should usually at least be supplied with a phase guess so that it may manufacture an appropriate density guess. density() manufactures the initial density guess, nondimensionalizes everything, and then calls WaterPropsIAPWSphi::dfind(), which does the iterative calculation to find the density condition that matches the desired input pressure.

Parameters

pressure	Pressure in Pascals (Newton/m**2)
phase	guessed phase of water; -1: no guessed phase
rhoguess	guessed density of the water; -1.0: no guessed density

Returns: the density. If an error is encountered in the calculation the value of -1.0 is returned.

Definition at line 138 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, Cantera::M_water, WaterPropsIAPWS::pressure(), Cantera::Rgas, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by WaterPropsIAPWS::densSpinodalSteam(), and WaterPropsIAPWS::densSpinodalWater().

◆ density() [2/2]

doublereal density ( ) const

Returns the density (kg m-3)

The density is an independent variable in the underlying equation of state

Returns: the density (kg m-3)

Definition at line 192 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, and Cantera::Rho_c.

Referenced by WaterPropsIAPWS::corr(), WaterPropsIAPWS::corr1(), and WaterPropsIAPWS::psat().

◆ temperature()

doublereal temperature ( ) const

Returns the temperature (Kelvin)

Returns: s the internally stored temperature

Definition at line 197 of file WaterPropsIAPWS.cpp.

References Cantera::T_c, and WaterPropsIAPWS::tau.

Referenced by WaterPropsIAPWS::calcDim(), WaterPropsIAPWS::corr(), WaterPropsIAPWS::corr1(), WaterPropsIAPWS::density(), WaterPropsIAPWS::density_const(), WaterPropsIAPWS::densSpinodalSteam(), WaterPropsIAPWS::densSpinodalWater(), WaterPropsIAPWS::dpdrho(), WaterPropsIAPWS::enthalpy(), WaterPropsIAPWS::Gibbs(), WaterPropsIAPWS::helmholtzFE(), WaterPropsIAPWS::intEnergy(), WaterPropsIAPWS::pressure(), WaterPropsIAPWS::psat(), and WaterPropsIAPWS::setState_TR().

◆ coeffThermExp()

doublereal coeffThermExp ( ) const

Returns the coefficient of thermal expansion.

alpha = d (ln V) / dT at constant P.

Returns: the coefficient of thermal expansion

Definition at line 259 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::isothermalCompressibility().

Referenced by PDSS_Water::dthermalExpansionCoeffdT(), PDSS_Water::thermalExpansionCoeff(), and WaterSSTP::thermalExpansionCoeff().

◆ coeffPresExp()

doublereal coeffPresExp ( ) const

Returns the isochoric pressure derivative wrt temperature.

beta = M / (rho * Rgas) (d (pressure) / dT) at constant rho

Note for ideal gases this is equal to one.

beta = delta (phi0_d() + phiR_d()) - tau delta (phi0_dt() + phiR_dt())

Definition at line 254 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWSphi::dimdpdT(), WaterPropsIAPWS::m_phi, and WaterPropsIAPWS::tau.

◆ isothermalCompressibility()

doublereal isothermalCompressibility ( ) const

Returns the coefficient of isothermal compressibility for the state of the object.

kappa = - d (ln V) / dP at constant T.

units - 1/Pascal

Returns: the isothermal compressibility

Definition at line 240 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWS::dpdrho(), and Cantera::Rho_c.

Referenced by WaterPropsIAPWS::coeffThermExp(), PDSS_Water::isothermalCompressibility(), and WaterSSTP::isothermalCompressibility().

◆ dpdrho()

doublereal dpdrho ( ) const

Returns the value of dp / drho at constant T for the state of the object.

units - Joules / kg

Returns: dpdrho

Definition at line 247 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWSphi::dimdpdrho(), WaterPropsIAPWS::m_phi, Cantera::M_water, Cantera::Rgas, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by WaterPropsIAPWS::isothermalCompressibility().

◆ psat_est()

doublereal psat_est ( doublereal temperature ) const

This function returns an estimated value for the saturation pressure.

It does this via a polynomial fit of the vapor pressure curve. units = (Pascals)

Parameters

temperature Input temperature (Kelvin)

Returns: the estimated saturation pressure

Definition at line 202 of file WaterPropsIAPWS.cpp.

Referenced by WaterPropsIAPWS::densSpinodalSteam(), WaterPropsIAPWS::densSpinodalWater(), and PDSS_Water::pref_safe().

◆ psat()

doublereal psat	(	doublereal	temperature,
		int	waterState = `WATER_LIQUID`
	)

This function returns the saturation pressure given the temperature as an input parameter, and sets the internal state to the saturated conditions.

Note this function will return the saturation pressure, given the temperature. It will then set the state of the system to the saturation condition. The input parameter waterState is used to either specify the liquid state or the gas state at the desired temperature and saturated pressure.

If the input temperature, T, is above T_c, this routine will set the internal state to T and the pressure to P_c. Then, return P_c.

Parameters

temperature	input temperature (kelvin)
waterState	integer specifying the water state

Returns: the saturation pressure. units = Pascal

Definition at line 323 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::density(), Cantera::P_c, Cantera::T_c, and WaterPropsIAPWS::temperature().

Referenced by PDSS_Water::satPressure(), and WaterSSTP::satPressure().

◆ densSpinodalWater()

doublereal densSpinodalWater ( ) const

Return the value of the density at the water spinodal point (on the liquid side) for the current temperature.

Returns: the density with units of kg m-3

Definition at line 405 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWS::density_const(), WaterPropsIAPWS::psat_est(), Cantera::Rho_c, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

◆ densSpinodalSteam()

doublereal densSpinodalSteam ( ) const

Return the value of the density at the water spinodal point (on the gas side) for the current temperature.

Returns: the density with units of kg m-3

Definition at line 493 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWS::density_const(), WaterPropsIAPWS::psat_est(), Cantera::Rho_c, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

◆ phaseState()

int phaseState ( bool checkState = false ) const

Returns the Phase State flag for the current state of the object.

Parameters

checkState If true, this function does a complete check to see where in parameters space we are

There are three values:

WATER_GAS below the critical temperature but below the critical density
WATER_LIQUID below the critical temperature but above the critical density
WATER_SUPERCRIT above the critical temperature

Definition at line 365 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::iState, and WaterPropsIAPWS::tau.

Referenced by WaterSSTP::phaseOfMatter().

◆ Tcrit()

doublereal Tcrit ( ) const

inline

Returns the critical temperature of water (Kelvin)

This is hard coded to the value 647.096 Kelvin

Definition at line 380 of file WaterPropsIAPWS.h.

Referenced by PDSS_Water::critTemperature(), WaterSSTP::critTemperature(), PDSS_Water::pref_safe(), and WaterSSTP::vaporFraction().

◆ Pcrit()

doublereal Pcrit ( ) const

inline

Returns the critical pressure of water (22.064E6 Pa)

This is hard coded to the value of 22.064E6 pascals

Definition at line 388 of file WaterPropsIAPWS.h.

Referenced by PDSS_Water::critPressure(), WaterSSTP::critPressure(), and PDSS_Water::pref_safe().

◆ Rhocrit()

doublereal Rhocrit ( ) const

inline

Return the critical density of water (kg m-3)

This is equal to 322 kg m-3.

Definition at line 396 of file WaterPropsIAPWS.h.

Referenced by PDSS_Water::critDensity(), WaterSSTP::critDensity(), and WaterSSTP::vaporFraction().

◆ calcDim()

void calcDim	(	doublereal	temperature,
		doublereal	rho
	)

private

Calculate the dimensionless temp and rho and store internally.

Parameters

temperature	input temperature (kelvin)
rho	density in kg m-3

Definition at line 45 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::delta, WaterPropsIAPWS::iState, Cantera::Rho_c, Cantera::T_c, WaterPropsIAPWS::tau, and WaterPropsIAPWS::temperature().

Referenced by WaterPropsIAPWS::setState_TR().

◆ corr()

void corr	(	doublereal	temperature,
		doublereal	pressure,
		doublereal &	densLiq,
		doublereal &	densGas,
		doublereal &	delGRT
	)

private

Utility routine in the calculation of the saturation pressure.

Calculate the Gibbs free energy in mks units of J kmol-1 K-1.

Parameters

temperature	temperature (kelvin)
pressure	pressure (Pascal)
densLiq	Output density of liquid
densGas	output Density of gas
delGRT	output delGRT

Definition at line 274 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::density(), WaterPropsIAPWS::pressure(), and WaterPropsIAPWS::temperature().

◆ corr1()

void corr1	(	doublereal	temperature,
		doublereal	pressure,
		doublereal &	densLiq,
		doublereal &	densGas,
		doublereal &	pcorr
	)

private

Utility routine in the calculation of the saturation pressure.

Parameters

temperature	temperature (kelvin)
pressure	pressure (Pascal)
densLiq	Output density of liquid
densGas	output Density of gas
pcorr	output corrected pressure

Definition at line 298 of file WaterPropsIAPWS.cpp.

References WaterPropsIAPWS::density(), WaterPropsIAPWS::pressure(), and WaterPropsIAPWS::temperature().

Member Data Documentation

◆ m_phi

WaterPropsIAPWSphi m_phi

mutableprivate

pointer to the underlying object that does the calculations.

Definition at line 433 of file WaterPropsIAPWS.h.

Referenced by WaterPropsIAPWS::coeffPresExp(), WaterPropsIAPWS::cp(), WaterPropsIAPWS::cv(), WaterPropsIAPWS::dpdrho(), WaterPropsIAPWS::enthalpy(), WaterPropsIAPWS::entropy(), WaterPropsIAPWS::Gibbs(), WaterPropsIAPWS::helmholtzFE(), WaterPropsIAPWS::intEnergy(), WaterPropsIAPWS::pressure(), and WaterPropsIAPWS::setState_TR().

◆ tau

doublereal tau

private

Dimensionless temperature, tau = T_C / T.

Definition at line 436 of file WaterPropsIAPWS.h.

Referenced by WaterPropsIAPWS::calcDim(), WaterPropsIAPWS::coeffPresExp(), WaterPropsIAPWS::density_const(), WaterPropsIAPWS::densSpinodalSteam(), WaterPropsIAPWS::densSpinodalWater(), WaterPropsIAPWS::dpdrho(), WaterPropsIAPWS::enthalpy(), WaterPropsIAPWS::Gibbs(), WaterPropsIAPWS::helmholtzFE(), WaterPropsIAPWS::intEnergy(), WaterPropsIAPWS::phaseState(), WaterPropsIAPWS::pressure(), WaterPropsIAPWS::setState_TR(), and WaterPropsIAPWS::temperature().

◆ delta

doublereal delta

mutableprivate

Dimensionless density, delta = rho / rho_c.

Definition at line 439 of file WaterPropsIAPWS.h.

Referenced by WaterPropsIAPWS::calcDim(), WaterPropsIAPWS::coeffPresExp(), WaterPropsIAPWS::density(), WaterPropsIAPWS::density_const(), WaterPropsIAPWS::densSpinodalSteam(), WaterPropsIAPWS::densSpinodalWater(), WaterPropsIAPWS::dpdrho(), WaterPropsIAPWS::helmholtzFE(), WaterPropsIAPWS::isothermalCompressibility(), WaterPropsIAPWS::molarVolume(), WaterPropsIAPWS::pressure(), and WaterPropsIAPWS::setState_TR().

◆ iState

int iState

mutableprivate

Current state of the system.

Definition at line 442 of file WaterPropsIAPWS.h.

Referenced by WaterPropsIAPWS::calcDim(), and WaterPropsIAPWS::phaseState().

The documentation for this class was generated from the following files:

Public Member Functions

Private Member Functions

Private Attributes

Detailed Description

Constructor & Destructor Documentation

◆ WaterPropsIAPWS()

Member Function Documentation

◆ setState_TR()

◆ helmholtzFE()

◆ Gibbs()

◆ enthalpy()

◆ intEnergy()

◆ entropy()

◆ cv()

◆ cp()

◆ molarVolume()

◆ pressure()

◆ density() [1/2]

◆ density_const()

◆ density() [2/2]

◆ temperature()

◆ coeffThermExp()

◆ coeffPresExp()

◆ isothermalCompressibility()

◆ dpdrho()

◆ psat_est()

◆ psat()

◆ densSpinodalWater()

◆ densSpinodalSteam()

◆ phaseState()

◆ Tcrit()

◆ Pcrit()

◆ Rhocrit()

◆ calcDim()

◆ corr()

◆ corr1()

Member Data Documentation

◆ m_phi

◆ tau

◆ delta

◆ iState